Gazprom recently said it had completely suspended gas supplies to Bulgarian Gas company and Polish Oil and Gas Company (PGNiG) because it was not being paid in rubles. Russia said it would resume gas supplies after it agreed to pay for them in rubles.
Bulgaria and Poland announced Monday that they have received a notice from Russia to suspend natural gas supplies from Monday.
Russian President Vladimir Putin on March 31 signed a presidential decree to settle gas trade with "unfriendly" countries and regions in rubles. When the new rules took effect on April 1, Presidential press secretary Dmitry Peskov said Russia would not immediately "cut off gas" to Europe, as the cost of gas supplies starting April 1 should be settled in the second half of April or May.
Because of the ever-changing international situation, the supply and prices of international bulk Silicon Nitride, Silicon Nitride Overview, Silicon Nitride Applications, Silicon Nitride Suppliers, Silicon Nitride Price are still very uncertain.
Overview of Silicon Nitride Si3N4
Silicon nitride is a compound of silicon and nitrogen. Si3N4 is the most thermodynamically stable in silicon nitride. It is a white, high melting solid, relatively chemically inert, attacked by dilute HF and hot H2SO4. It works very hard (MoHS is 8.5) and has high thermal stability.
How is silicon nitride Si3N4 powder produced?
Hexagonal β-Si3N4 can be directly carried out with silicon nitride and nitrogen can be carried out at 100-1400 °C.
SiCL4(L)+6NH3(g)→Si(NH)2(S)+4NH4Cl(S) at 0℃
3 Si(NH)2(S)→Si3N4(S)+N2(g)+3H2(g) at 1000℃
Or thermal reduction reaction with carbon under nitrogen atmosphere at 1400-1450 ℃ under nitrogen atmosphere:
However, if the silicon raw material used is of high purity, it will cause silicon nitride to contain impurities such as silicate and iron. The silicon nitride synthesized by the decomposition of diamine is amorphous and needs to be further annealed at 1400-1500 ℃ in nitrogen to be converted into crystalline powder. Only the decomposition of diamine is important. Silicon nitride is commercially produced by the nitridation process. Carbothermal reduction reaction is the simplest method for producing silicon nitride, and it is also the most economical and efficient method for manufacturing silicon powder in industry.
Electronic grade silicon nitride films using chemical vapor deposition or plasma enhanced chemical vapor deposition techniques
3 SiH4 (G) + 4 NH3 (g) → Si3N4 (S) + 12 H2 (g)
3 SiCL4 (G) + 4 NH3 (g) → Si3N4 (S) + 12 HCl (g)
3 SiCL2H2 (G) + 4 NH3 (g) → Si3N4 (S) + 6 HCl (g) + 6 H2 (g)
Application of silicon nitride Si3N4 powder
1) Manufacturing structural devices: metallurgy, machinery, aviation, aerospace, etc.
2) Surface treatment of metals and other materials: such as molds, tools, turbine blades.
3) Composite materials: such as metal, ceramic and graphite composite materials, rubber, plastics.
4) Colorless, transparent, self-lubricating and wear-resistant nanoparticle film for advanced surface protection such as mobile phones and automobiles.
5) Ball bearings.
6) Ball valve and parts.
7) Corrosion resistant turbine.
The price of silicon nitride Si3N4 powder
The price of silicon nitride Si3N4 powder will change randomly with the production cost, transportation cost, international situation, exchange rate and the supply and demand of the silicon nitride Si3N4 powder market. Tanki New Materials Co.,Ltd. aims to help industries and chemical wholesalers find high-quality, low-cost nanomaterials and chemicals by providing a full range of customized services. If you are looking for Silicon Nitride Si3N4 Powder, please feel free to send an inquiry to get the latest price of Silicon Nitride Si3N4 Powder.
Silicon Nitride Si3N4 Powder Supplier
As a global supplier of silicon nitride Si3N4 powder, Tanki New Materials Co.,Ltd. has extensive experience in the performance, application and cost-effective manufacturing of advanced engineering materials. The company has successfully developed a series of powder materials (titanium nitride, silicon nitride, titanium nitride, etc.) high-purity targets, functional ceramics and structural devices, and provides OEM services.
Chemical Composition of Silicon Nitride Si3N4 Powder
The day after the shooting at a Texas elementary school, the National Rifle Association issued a statement saying it "extends its deepest sympathies to the families and victims involved in this terrible and evil crime," adding it would "reflect on these events and pray for the victims."
It comes just days before the National Rifle Association's annual convention in Houston, Texas. Houston is less than five hours away. Texas Governor Tony Abbott, Senator Ted Cruz, and others are scheduled to attend the event, which has also caused a lot of controversies.
Texas Democratic gubernatorial candidate Mark O 'Rourke took to social media to call on Abbott to pull out of the convention, urging that it be held outside Texas. Many American netizens also took to social media to express their dissatisfaction. "I wish the NRA's annual meeting was held three days after 19 children and two adults were massacred," said one. "The school shooting was not a lone Wolf, but with the help of the NRA."
Between 2000 and 2020, US gun manufacturers produced more than 139 million guns for the civilian market, according to the Justice Department report. The NATIONAL Rifle Association (NRA) is one of the leading gun rights advocates with more than 5m members and deep pockets. The United States has not passed major gun control laws for more than two decades, blocked by gun interests.
The Silicon Nitride, Silicon Nitride Overview, Silicon Nitride Applications, Silicon Nitride Suppliers, Silicon Nitride Price price is predicted to increase in the next few days.
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